According to 2001/58/EC
MATERIAL SAFETY DATA SHEET
Catalogue N° : 05001D08 Printing date : 20/05/2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1. Identification of the substance or preparation
EP 7 N
1.2. Use of the substance/preparation
Developer for positive offset printing plates
1.3. Company/undertaking identification
FUJIFILM Europe NV
EUROPARK-NOORD 21-22
B-9100 SINT NIKLAAS
TEL : +32 (3)760 02 00
FAX : +32 (3)776 91 22
1.4. Emergency telephone
+32 (0)3 760 02 00
2. COMPOSITION / INFORMATION ON INGREDIENTS
Aqueous solution.
Components contributing to hazard:
w/w%
CAS N°
EINECS N°
Chemical Name
Symb.R-phrases
7-15
.
1-5
.
0,5-1,5
.
10006-28-7
.
107-98-2
.
64-02-8
.
253-001-1
.
203-539-1
.
200-573-9
.
DIPOTASSIUM SILICATE
C R:34-37
1-METHOXY-2-PROPANOL
- R:10
ETHYLENEDIAMINETETRAACETATE, TETRASODIUMSALT
Xn R:22-36-52/53
3. HAZARDS IDENTIFICATION
Most important hazards :
Causes burns.
4. FIRST AID MEASURES
Eye contact
Irrigate with flowing water immediately and continuously for 15 minutes.
Consult medical personnel.
Skin contact
Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing
Ingestion
Consult a physician or transport to emergency facility immediately
Do not induce vomitting. Give large amounts of water or milk if available
and transport to medical facility.
Inhalation
Remove to fresh air. Consult a physician.
Further information
None
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media:
Water.
Water fog, carbon dioxide, foam, dry chemicals.
5.2. Extinguishing media to avoid:
None under normal conditions.
5.3. Further information:
Keep containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES
- Wear adequate personal protective equipment, see section 8 ( exposure
control / personal protection ).
- Spills should be contained by and carried with suitable absorbent
material and removed from disposal.
- Dispose of according to local and national regulations.
- Prevent from entering into soil, waterways and groundwater.
7. HANDLING AND STORAGE
7.1. Handling
Avoid eye and skin contact. Wash hands and exposed skin before eating,
drinking or smoking and after work. Use only in a well ventilated area.
Ingestion, exposure to skin and eyes and inhalation of any generated
vapours should be avoided. Wear suitable protective clothing, gloves and
eye/face protection. Do not consume or store food in the working area.
7.2. Storage
Keep containers tightly closed. Store in a well ventilated, cool, dry area.
Storage class : 8B (VCI storage system).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure limit values (INGREDIENTS INFORMATION)
1-METHOXY-2-PROPANOL
MAK ( Deutschland, TRGS 900 ) = 100 ppm - 370 mg/m³
TLV-TWA = 100 ppm - 374 mg/m³
TLV-STEL = 150 ppm - 561 mg/m³
ETHYLENEDIAMINETETRAACETATE, TETRASODIUMSALT
MAK ( Deutschland, TRGS 900 ) = NAv
8.2. Exposure controls
Respiratory protection: no respiratory protection needed under normal
conditions. Good ventilation should be sufficient.
Hand protection: use chemical resistant gloves. In case of prolonged
immersion or frequently repeated contact use gloves made of the materials:
nitrile rubber (thickness >= 0,38 mm, breakthrough time > 480 min)
neoprene (thickness >= 0,65 mm, breakthrough time > 240 min).
butyl rubber (thickness >= 0,36 mm, breakthrough time > 480 min)
For intermittent splash protection corresponding gloves with breakthrough
time > 60 min can be used.
Avoid gloves made of : natural rubber.
Eye protection: use chemical safety goggles. Eye wash fountain should be
located in immediate work area.
Other: appropriate protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : Colourless
Odour : Mild
Boiling point/range : ~ 100 °C
pH value (25°C) : 13,2
Vapour pressure (20°C) : ~ 23 mbar
Density (20°C) Kg/L : 1,152
Solubility in water (25°C) : Completely Soluble
10. STABILITY AND REACTIVITY
10.1. Conditions to avoid
The product is stable under normal storage conditions.
10.2. Materials to avoid
Keep away from acids.
10.3. Hazardous decomposition products
None.
11. TOXICOLOGICAL INFORMATION
Acute toxicity (INGREDIENTS INFORMATION)
1-METHOXY-2-PROPANOL
LD50 (Oral Rat) = 5000 mg/kg
ETHYLENEDIAMINETETRAACETATE, TETRASODIUMSALT
LD50 (Oral Rat) = NAv
Eye contact
Causes burns.
Skin contact
Causes burns.
Ingestion
Causes burns.
Inhalation
Causes burns.
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity
1-METHOXY-2-PROPANOL
LC50 (Leuciscus idus, orfe, 96h) = 4600 mg/L
ETHYLENEDIAMINETETRAACETATE, TETRASODIUMSALT
LD50 (Dermal rabbit) = NAv
12.2. Mobility
not known
12.3. Persistence and Degradability
not known
12.4. Bioaccumulative potential
not known
12.5. Other adverse effects
13. DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations. Containers must be
disposed of in accordance with local regulations.
EWC : 06 03 14 Solid salts and solutions other than those mentioned in
06 03 11 and 06 03 13.
14. TRANSPORT INFORMATION
UN N° : 3266 PSN : CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S.
(Alkali silicates)
ADR/RID
Class:8 labels :8 Pack. Group:II
Code :E TREMcard :8.3266C-200 Spec. Prov.:274
Pack. Inst.:P001,IBC02 Lim. Quant.:LQ22
IMDG
Class:8 Subs. Risk :NA Pack. Group:II
EmS fire:F-A EmS Storage:S-B IBC. Inst. :IBC02
Pack. Inst.:P001 Lim. Quant.:1L Mar.Poll:N
ICAO/IATA
Class:8 Subs. Risk :NA Pack. Group:II
Passenger and Cargo Aircraft. Pkg Inst:808 Max Net Qty/Pkg:1L
Cargo Aircraft Only . Pkg Inst:812 Max Net Qty/Pkg:30L
Ltd Qty . Pkg Inst:0.5L Max Net Qty/Pkg:Y808
15. REGULATORY INFORMATION
EU Classification and User Label Information:
Contains : DIPOTASSIUM SILICATE
Symbol(s) : C
R(isk) phrase(s) :
R34 : Causes burns.
S(afety) phrase(s) :
S26 : In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45 : In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Other information :
WGK: 1
16. OTHER INFORMATION
The use of the preparation is restricted to professional users|
The above mentioned data correspond to our present state of knowledge and
experience. The safety data sheet serves as description of the products in
regard to necessary safety measures. The indications have not the meaning
of guarantees on properties.
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Date of issue: 07.09.2006
Supersedes edition of: 01.10.2005
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RISK PHRASES MENTIONED IN PARAGRAPH 2:
R10 : Flammable.
R22 : Harmful if swallowed.
R34 : Causes burns.
R36 : Irritating to eyes.
R37 : Irritating to respiratory system.
R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
